Ferbam
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    WARNING: This product is for research use only, not for human or veterinary use.

Hodoodo CAT#: H591911

CAS#: 14484-64-1

Description: Ferbam is a pesticide.


Chemical Structure

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Ferbam
CAS# 14484-64-1

Theoretical Analysis

Hodoodo Cat#: H591911
Name: Ferbam
CAS#: 14484-64-1
Chemical Formula: C9H24FeN3S6
Exact Mass: 421.96
Molecular Weight: 422.520
Elemental Analysis: C, 25.58; H, 5.73; Fe, 13.22; N, 9.95; S, 45.53

Price and Availability

Size Price Availability Quantity
1g USD 250 2 Weeks
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Synonym: Ferbam; Trifungol; Trimanzone

IUPAC/Chemical Name: Iron, tris(dimethylcarbamodithioato-kappaS,kappaS')-, (OC-6-11)-

InChi Key: QKOADSGUNBXFQH-UHFFFAOYSA-Q

InChi Code: InChI=1S/3C3H7NS2.Fe/c3*1-4(2)3(5)6;/h3*1-2H3,(H,5,6);/q;;;-3/p+3

SMILES Code: CN(C1=S[Fe+3]23([SH-]C(N(C)C)=S3)([SH-]1)[SH-]C(N(C)C)=S2)C

Appearance: Solid powder

Purity: >97% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >3 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.03.00

More Info:

Biological target:
In vitro activity:
In vivo activity:

Preparing Stock Solutions

The following data is based on the product molecular weight 422.52 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
Formulation protocol:
In vitro protocol:
In vivo protocol:

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1: Lee M, Oh K, Choi HK, Lee SG, Youn HJ, Lee HL, Jeong DH. Subnanomolar Sensitivity of Filter Paper-Based SERS Sensor for Pesticide Detection by Hydrophobicity Change of Paper Surface. ACS Sens. 2018 Jan 26;3(1):151-159. doi: 10.1021/acssensors.7b00782. Epub 2018 Jan 12. PubMed PMID: 29282983.

2: Yang T, Zhao B, Kinchla AJ, Clark JM, He L. Investigation of Pesticide Penetration and Persistence on Harvested and Live Basil Leaves Using Surface-Enhanced Raman Scattering Mapping. J Agric Food Chem. 2017 May 3;65(17):3541-3550. doi: 10.1021/acs.jafc.7b00548. Epub 2017 Apr 24. PubMed PMID: 28393527.

3: Al-Alam J, Bom L, Chbani A, Fajloun Z, Millet M. Analysis of Dithiocarbamate Fungicides in Vegetable Matrices Using HPLC-UV Followed by Atomic Absorption Spectrometry. J Chromatogr Sci. 2017 Apr 1;55(4):429-435. doi: 10.1093/chromsci/bmw198. PubMed PMID: 27999077.

4: Yang T, Zhao B, Hou R, Zhang Z, Kinchla AJ, Clark JM, He L. Evaluation of the Penetration of Multiple Classes of Pesticides in Fresh Produce Using Surface-Enhanced Raman Scattering Mapping. J Food Sci. 2016 Oct 6. doi: 10.1111/1750-3841.13520. [Epub ahead of print] PubMed PMID: 27711977.

5: Hou R, Zhang Z, Pang S, Yang T, Clark JM, He L. Alteration of the Nonsystemic Behavior of the Pesticide Ferbam on Tea Leaves by Engineered Gold Nanoparticles. Environ Sci Technol. 2016 Jun 21;50(12):6216-23. doi: 10.1021/acs.est.6b01336. Epub 2016 Jun 8. PubMed PMID: 27254832.

6: Yang T, Zhang Z, Zhao B, Hou R, Kinchla A, Clark JM, He L. Real-Time and in Situ Monitoring of Pesticide Penetration in Edible Leaves by Surface-Enhanced Raman Scattering Mapping. Anal Chem. 2016 May 17;88(10):5243-50. doi: 10.1021/acs.analchem.6b00320. Epub 2016 May 2. PubMed PMID: 27099952.

7: Gao S, Glasser J, He L. A Filter-based Surface Enhanced Raman Spectroscopic Assay for Rapid Detection of Chemical Contaminants. J Vis Exp. 2016 Feb 19;(108):53791. doi: 10.3791/53791. PubMed PMID: 26966831; PubMed Central PMCID: PMC4828175.

8: Guo H, Xing B, Hamlet LC, Chica A, He L. Surface-enhanced Raman scattering detection of silver nanoparticles in environmental and biological samples. Sci Total Environ. 2016 Jun 1;554-555:246-52. doi: 10.1016/j.scitotenv.2016.02.084. Epub 2016 Mar 5. PubMed PMID: 26956173.

9: Guo H, Zhang Z, Xing B, Mukherjee A, Musante C, White JC, He L. Analysis of silver nanoparticles in antimicrobial products using surface-enhanced Raman spectroscopy (SERS). Environ Sci Technol. 2015 Apr 7;49(7):4317-24. doi: 10.1021/acs.est.5b00370. Epub 2015 Mar 26. PubMed PMID: 25775209.

10: Zheng J, Pang S, Labuza TP, He L. Semi-quantification of surface-enhanced Raman scattering using a handheld Raman spectrometer: a feasibility study. Analyst. 2013 Dec 7;138(23):7075-8. doi: 10.1039/c3an01450a. Epub 2013 Sep 24. PubMed PMID: 24066350.

11: Schmidt B, Christensen HB, Petersen A, Sloth JJ, Poulsen ME. Method validation and analysis of nine dithiocarbamates in fruits and vegetables by LC-MS/MS. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2013;30(7):1287-98. doi: 10.1080/19440049.2013.801083. Epub 2013 Jun 25. PubMed PMID: 23799268.

12: Saute B, Premasiri R, Ziegler L, Narayanan R. Gold nanorods as surface enhanced Raman spectroscopy substrates for sensitive and selective detection of ultra-low levels of dithiocarbamate pesticides. Analyst. 2012 Nov 7;137(21):5082-7. doi: 10.1039/c2an36047k. Epub 2012 Sep 14. PubMed PMID: 22977883.

13: Zaijun L, You F, Zhongyun L, Jian T. Spectrophotometric determination of iron(III)-dimethyldithiocarbamate (ferbam) using 9-(4-carboxyphenyl)-2,3,7-trihydroxyl-6-fluorone. Talanta. 2004 Jun 17;63(3):647-51. doi: 10.1016/j.talanta.2003.12.007. PubMed PMID: 18969482.

14: Agarwal S, Aggarwal SG, Singh P. Specific determination of ferbam residues in fog-water. Talanta. 2003 Dec 23;61(6):871-7. doi: 10.1016/S0039-9140(03)00372-2. PubMed PMID: 18969253.

15: Rath NC, Huff WE, Huff GR, Kannan L. Induction of tibial dyschondroplasia by carbamate and thiocarbamate pesticides. Avian Dis. 2007 Jun;51(2):590-3. PubMed PMID: 17626489.

16: Aulakh JS, Fekete A, Malik AK, Mahajan RK, Schmitt-Kopplin P. Capillary electrophoretic-ultraviolet method for the separation and estimation of zineb, maneb, and ferbam in food samples. J AOAC Int. 2007 May-Jun;90(3):834-7. PubMed PMID: 17580637.

17: Tilton F, La Du JK, Vue M, Alzarban N, Tanguay RL. Dithiocarbamates have a common toxic effect on zebrafish body axis formation. Toxicol Appl Pharmacol. 2006 Oct 1;216(1):55-68. Epub 2006 May 16. PubMed PMID: 16797628.

18: Michaud JP. Responses of two ladybeetles to eight fungicides used in Florida citrus: implications for biological control. J Insect Sci. 2001;1:6. Epub 2001 May 15. PubMed PMID: 15455066; PubMed Central PMCID: PMC355890.

19: Malik AK, Bansal S, Aulakh JS. Fourth-derivative spectrophotometric determination of fungicide ferbam (iron(III) dimethyldithiocarbamate) in a commercial sample and wheat grains using 2,2'-bipyridyl. Anal Bioanal Chem. 2003 Apr;375(8):1250-3. Epub 2003 Mar 18. PubMed PMID: 12733047.

20: Shanthi R, Krishnamoorthy M. Evaluation of the aneugenic potential of the fungicide Ferbam in mice. Teratog Carcinog Mutagen. 2002;22(6):451-9. PubMed PMID: 12395406.