Bromopropylate

    WARNING: This product is for research use only, not for human or veterinary use.

Hodoodo CAT#: H571464

CAS#: 18181-80-1

Description: Bromopropylate is an insecticide that is the active substance in fumigant strips for mites.

Chemical Structure

img
Bromopropylate
CAS# 18181-80-1
Instruction

Theoretical Analysis

Hodoodo Cat#: H571464
Name: Bromopropylate
CAS#: 18181-80-1
Chemical Formula: C17H16Br2O3
Exact Mass: 425.95
Molecular Weight: 428.120
Elemental Analysis: C, 47.69; H, 3.77; Br, 37.33; O, 11.21

Price and Availability

Size Price Availability Quantity
250mg USD 188
Bulk inquiry

Synonym: Bromopropylate; Acarol

IUPAC/Chemical Name: Benzeneacetic acid, 4-bromo-alpha-(4-bromophenyl)-alpha-hydroxy-, 1-methylethyl ester

InChi Key: FOANIXZHAMJWOI-UHFFFAOYSA-N

InChi Code: InChI=1S/C17H16Br2O3/c1-11(2)22-16(20)17(21,12-3-7-14(18)8-4-12)13-5-9-15(19)10-6-13/h3-11,21H,1-2H3

SMILES Code: O=C(OC(C)C)C(O)(C1=CC=C(Br)C=C1)C2=CC=C(Br)C=C2

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >2 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

More Info:

Biological target:
In vitro activity:
In vivo activity:

Preparing Stock Solutions

The following data is based on the product molecular weight 428.12 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
Formulation protocol:
In vitro protocol:
In vivo protocol:

Molarity Calculator

Calculate the mass, volume, or concentration required for a solution.
=
x
x
g/mol

*When preparing stock solutions always use the batch-specific molecular weight of the product found on the vial label and SDS / CoA (available online).

Reconstitution Calculator

The reconstitution calculator allows you to quickly calculate the volume of a reagent to reconstitute your vial. Simply enter the mass of reagent and the target concentration and the calculator will determine the rest.

=
÷

Dilution Calculator

Calculate the dilution required to prepare a stock solution.
x
=
x

1: Zhang Q, Liu C, Wu N, Wu X, Li S. [Determination of propargite, tebuconazole and bromopropylate pesticide residues in Taiwan green jujubes by gas chromatography-tandem mass spectrometry]. Se Pu. 2014 Aug;32(8):886-9. Chinese. PubMed PMID: 25434127.

2: Kostka G, Kopeć-Szlezak J, Palut D. Early hepatic changes induced in rats by two hepatocarcinogenic organohalogen pesticides: bromopropylate and DDT. Carcinogenesis. 1996 Mar;17(3):407-12. PubMed PMID: 8631124.

3: Barba A, Camara MA, Navarro Garcia S, Sanchez-Fresneda C, Lopez de Hierro N, Acebes A. Disappearance of bromopropylate residues in artichokes, strawberries and beans. J Environ Sci Health B. 1991 Jun;26(3):323-32. PubMed PMID: 1894918.

4: Ramón-Azcón J, Sánchez-Baeza F, Sanvicens N, Marco MP. Development of an enzyme-linked immunosorbent assay for determination of the miticide bromopropylate. J Agric Food Chem. 2009 Jan 28;57(2):375-84. doi: 10.1021/jf802821n. PubMed PMID: 19113903.

5: Thomas H, Sagelsdorff P, Molitor E, Skripsky T, Waechter F. Bromopropylate: induction of hepatic cytochromes P450 and absence of covalent binding to DNA in mouse liver. Toxicol Appl Pharmacol. 1994 Nov;129(1):155-62. PubMed PMID: 7974489.

6: Sadło S. Changes of bromopropylate and carbendazim residues during processing of apples into apple puree. Rocz Panstw Zakl Hig. 1996;47(3):273-6. PubMed PMID: 9008401.

7: Corta E, Bakkali A, Barranco A, Berrueta LA, Gallo B, Vicente F, Bogdanov S. Study of the degradation products of bromopropylate, chlordimeform, coumaphos, cymiazole, flumethrin and tau-fluvalinate in aqueous media. Talanta. 2000 Jun 21;52(2):169-80. PubMed PMID: 18967974.

8: Formica G. Gas chromatographic determination of residues of bromopropylate and two of its degradation products in honey. J Assoc Off Anal Chem. 1984 Sep-Oct;67(5):896-901. PubMed PMID: 6501151.

9: van Rillaer W, Beernaert H. Determination of residual bromopropylate and coumaphos in honey and honeycomb by capillary gas chromatography. Z Lebensm Unters Forsch. 1989 Feb;188(2):135-7. PubMed PMID: 2718634.

10: Knowles CO, Ahmad S. Comparative metabolism of chlorobenzilate, chloropropylate, and bromopropylate acaricides by rat hepatic enzymes. Can J Physiol Pharmacol. 1971 Jun;49(6):590-7. PubMed PMID: 5088463.

11: Jiménez JJ, Bernal JL, del Nozal MJ, Toribio L, Bernal J. Determination of impurities in pesticides and their degradation products formed during the wine-making process by solid-phase extraction and gas chromatography with detection by electron ionization mass spectrometry. II. Bromopropylate, trichlorphon, parathion-methyl and tebuconazole. Rapid Commun Mass Spectrom. 2004;18(22):2629-36. PubMed PMID: 15481093.

12: Liapis KS, Aplada-Sarlis P, Kyriakidis NV. Rapid multi-residue method for the determination of azinphos methyl, bromopropylate, chlorpyrifos, dimethoate, parathion methyl and phosalone in apricots and peaches by using negative chemical ionization ion trap technology. J Chromatogr A. 2003 May 9;996(1-2):181-7. PubMed PMID: 12830919.

13: Argarate N, Arestin M, Ramón-Azcón J, Alfaro B, Barranco A, Sánchez-Baeza F, Marco MP. Evaluation of immunoassays as an alternative for the rapid determination of pesticides in wine and grape samples. J AOAC Int. 2010 Jan-Feb;93(1):2-11. PubMed PMID: 20334160.

14: Jacobsen H, Østergaard G, Lam HR, Poulsen ME, Frandsen H, Ladefoged O, Meyer O. Repeated dose 28-day oral toxicity study in Wistar rats with a mixture of five pesticides often found as residues in food: alphacypermethrin, bromopropylate, carbendazim, chlorpyrifos and mancozeb. Food Chem Toxicol. 2004 Aug;42(8):1269-77. PubMed PMID: 15207377.

15: Ramón-Azcón J, Yasukawa T, Mizutani F. Sensitive and spatially multiplexed detection system based on dielectrophoretic manipulation of DNA-encoded particles used as immunoreactions platform. Anal Chem. 2011 Feb 1;83(3):1053-60. doi: 10.1021/ac102854z. Epub 2010 Dec 30. PubMed PMID: 21192674.

16: Tuzimski T, Rejczak T. Determination of pesticides in sunflower seeds by high-performance liquid chromatography coupled with a diode array detector. J AOAC Int. 2014 Jul-Aug;97(4):1012-20. PubMed PMID: 25145131.

17: Pelit L, Dizdaş TN. Preparation and application of a polythiophene solid-phase microextraction fiber for the determination of endocrine-disruptor pesticides in well waters. J Sep Sci. 2013 Oct;36(19):3234-41. doi: 10.1002/jssc.201300633. Epub 2013 Aug 29. PubMed PMID: 23913719.

18: Tsiropoulos NG, Amvrazi EG. Determination of pesticide residues in honey by single-drop microextraction and gas chromatography. J AOAC Int. 2011 Mar-Apr;94(2):634-44. PubMed PMID: 21563700.

19: Adamczyk S, Lázaro R, Pérez-Arquillué C, Bayarri S, Herrera A. Impact of the use of fluvalinate on different types of beeswax from Spanish hives. Arch Environ Contam Toxicol. 2010 Apr;58(3):733-9. doi: 10.1007/s00244-009-9387-7. Epub 2009 Sep 16. PubMed PMID: 19756841.

20: Amendola G, Pelosi P, Dommarco R. Solid-phase extraction for multi-residue analysis of pesticides in honey. J Environ Sci Health B. 2011;46(1):24-34. doi: 10.1080/03601234.2010.515170. PubMed PMID: 20936565.