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Fluopyram
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WARNING: This product is for research use only, not for human or veterinary use.

Hodoodo CAT#: H591238

CAS#: 658066-35-4

Description: Fluopyram is a fungicide.

Chemical Structure

Fluopyram

CAS# 658066-35-4

Instruction

Theoretical Analysis

Hodoodo Cat#: H591238
Name: Fluopyram
CAS#: 658066-35-4
Chemical Formula: C16H11ClF6N2O
Exact Mass: 396.05
Molecular Weight: 396.720
Elemental Analysis: C, 48.44; H, 2.79; Cl, 8.94; F, 28.73; N, 7.06; O, 4.03

Price and Availability

Size	Price	Availability	Quantity
50mg	USD 425
Bulk inquiry Welcome, Customer: Please do not inquire quote if your intended use is for a patient since our products are for research use and for chemical synthesis use, not for human use . For in-stock products, we listed price in the web page. You may inquire prices for which sizes were not listed. If no price is listed, this means the product is not in stock at the moment, which may be available via custom synthesis. For cost-effective reason, minimum order of 1g is requested (typically very expensive). The lead time is usually 2-4 months. Quote of less than 1g will not be provided. Hodoodo may not offer quote for below reasons: (1) current available synthetic method appears to be extremely expensive which is obviously not affordable to most customers; (2) Key raw material to make the product is temporally not available; (3) DEA controlled substances; (4) the product is under patent protection in customer’s country.

Synonym: Fluopyram;

IUPAC/Chemical Name: N-{2-(3-chloro-5-(trifluoromethyl)-2-pyridyl)ethyl}-alpha,alpha,alpha-trifluoro-o-toluamide

InChi Key: KVDJTXBXMWJJEF-UHFFFAOYSA-N

InChi Code: InChI=1S/C16H11ClF6N2O/c17-12-7-9(15(18,19)20)8-25-13(12)5-6-24-14(26)10-3-1-2-4-11(10)16(21,22)23/h1-4,7-8H,5-6H2,(H,24,26)

SMILES Code: O=C(NCCC1=NC=C(C(F)(F)F)C=C1Cl)C2=CC=CC=C2C(F)(F)F

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >2 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

More Info:

Instruction:

View handling instruction

Biological target:
In vitro activity:
In vivo activity:

Preparing Stock Solutions

The following data is based on the product molecular weight 396.72 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

Formulation protocol:
In vitro protocol:
In vivo protocol:

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1: Chawla S, Patel DJ, Patel SH, Kalasariya RL, Shah PG. Correction to: Behaviour and risk assessment of fluopyram and its metabolite in cucumber (Cucumis sativus) fruit and in soil. Environ Sci Pollut Res Int. 2018 Apr;25(12):11635. doi: 10.1007/s11356-018-1603-4. PubMed PMID: 29488198.

2: Mekonnen TF, Panne U, Koch M. Prediction of biotransformation products of the fungicide fluopyram by electrochemistry coupled online to liquid chromatography-mass spectrometry and comparison with in vitro microsomal assays. Anal Bioanal Chem. 2018 Apr;410(10):2607-2617. doi: 10.1007/s00216-018-0933-x. Epub 2018 Feb 17. PubMed PMID: 29455286.

3: Chawla S, Patel DJ, Patel SH, Kalasariya RL, Shah PG. Behaviour and risk assessment of fluopyram and its metabolite in cucumber (Cucumis sativus) fruit and in soil. Environ Sci Pollut Res Int. 2018 Apr;25(12):11626-11634. doi: 10.1007/s11356-018-1439-y. Epub 2018 Feb 10. Erratum in: Environ Sci Pollut Res Int. 2018 Feb 27;:. PubMed PMID: 29429109.

4: Wang X, Glawe DA, Kramer E, Weller D, Okubara PA. Biological Control of Botrytis cinerea: Interactions with Native Vineyard Yeasts from Washington State. Phytopathology. 2018 Jun;108(6):691-701. doi: 10.1094/PHYTO-09-17-0306-R. Epub 2018 Apr 26. PubMed PMID: 29334476.

5: Lv P, Chen Y, Zhao Z, Shi T, Wu X, Xue J, Li QX, Hua R. Design, Synthesis, and Antifungal Activities of 3-Acyl Thiotetronic Acid Derivatives: New Fatty Acid Synthase Inhibitors. J Agric Food Chem. 2018 Jan 31;66(4):1023-1032. doi: 10.1021/acs.jafc.7b05491. Epub 2018 Jan 16. PubMed PMID: 29290106.

6: Piechowicz B, Woś I, Podbielska M, Grodzicki P. The transfer of active ingredients of insecticides and fungicides from an orchard to beehives. J Environ Sci Health B. 2018 Jan 2;53(1):18-24. doi: 10.1080/03601234.2017.1369320. Epub 2017 Oct 30. PubMed PMID: 29083963.

7: Rotolo C, De Miccolis Angelini RM, Dongiovanni C, Pollastro S, Fumarola G, Di Carolo M, Perrelli D, Natale P, Faretra F. Use of biocontrol agents and botanicals in integrated management of Botrytis cinerea in table grape vineyards. Pest Manag Sci. 2018 Mar;74(3):715-725. doi: 10.1002/ps.4767. Epub 2017 Dec 11. PubMed PMID: 29044981.

8: Yamashita M, Fraaije B. Non-target site SDHI resistance is present as standing genetic variation in field populations of Zymoseptoria tritici. Pest Manag Sci. 2018 Mar;74(3):672-681. doi: 10.1002/ps.4761. Epub 2017 Nov 23. PubMed PMID: 29024365; PubMed Central PMCID: PMC5814837.

9: Scheurer M, Nödler K, Freeling F, Janda J, Happel O, Riegel M, Müller U, Storck FR, Fleig M, Lange FT, Brunsch A, Brauch HJ. Small, mobile, persistent: Trifluoroacetate in the water cycle - Overlooked sources, pathways, and consequences for drinking water supply. Water Res. 2017 Dec 1;126:460-471. doi: 10.1016/j.watres.2017.09.045. Epub 2017 Sep 26. PubMed PMID: 28992593.

10: Podbielska M, Szpyrka E, Piechowicz B, Zwolak A, Sadło S. Behavior of fluopyram and tebuconazole and some selected pesticides in ripe apples and consumer exposure assessment in the applied crop protection framework. Environ Monit Assess. 2017 Jul;189(7):350. doi: 10.1007/s10661-017-6057-5. Epub 2017 Jun 23. PubMed PMID: 28646436.

11: Malandrakis AA, Vattis KN, Markoglou AN, Karaoglanidis GS. Characterization of boscalid-resistance conferring mutations in the SdhB subunit of respiratory complex II and impact on fitness and mycotoxin production in Penicillium expansum laboratory strains. Pestic Biochem Physiol. 2017 May;138:97-103. doi: 10.1016/j.pestbp.2017.03.009. Epub 2017 Apr 11. PubMed PMID: 28456312.

12: Wei P, Liu Y, Li W, Qian Y, Nie Y, Kim D, Wang M. Corrigendum: Metabolic and Dynamic Profiling for Risk Assessment of Fluopyram, a Typical Phenylamide Fungicide Widely Applied in Vegetable Ecosystem. Sci Rep. 2017 Jan 25;7:41347. doi: 10.1038/srep41347. PubMed PMID: 28120927; PubMed Central PMCID: PMC5264616.

13: Wei P, Liu Y, Li W, Qian Y, Nie Y, Kim D, Wang M. Metabolic and Dynamic Profiling for Risk Assessment of Fluopyram, a Typical Phenylamide Fungicide Widely Applied in Vegetable Ecosystem. Sci Rep. 2016 Sep 22;6:33898. doi: 10.1038/srep33898. PubMed PMID: 27654708; PubMed Central PMCID: PMC5031996.

14: Patel BV, Chawla S, Gor H, Upadhyay P, Parmar KD, Patel AR, Shah PG. Residue decline and risk assessment of fluopyram + tebuconazole (400SC) in/on onion (Allium cepa). Environ Sci Pollut Res Int. 2016 Oct;23(20):20871-20881. Epub 2016 Aug 3. PubMed PMID: 27484201.

15: Bartlewicz J, Pozo MI, Honnay O, Lievens B, Jacquemyn H. Effects of agricultural fungicides on microorganisms associated with floral nectar: susceptibility assays and field experiments. Environ Sci Pollut Res Int. 2016 Oct;23(19):19776-86. doi: 10.1007/s11356-016-7181-4. Epub 2016 Jul 13. PubMed PMID: 27411538.

16: Dong B, Hu J. Photodegradation of the novel fungicide fluopyram in aqueous solution: kinetics, transformation products, and toxicity evolvement. Environ Sci Pollut Res Int. 2016 Oct;23(19):19096-106. doi: 10.1007/s11356-016-7073-7. Epub 2016 Jun 24. PubMed PMID: 27343079.

17: Faske TR, Hurd K. Sensitivity of Meloidogyne incognita and Rotylenchulus reniformis to Fluopyram. J Nematol. 2015 Dec;47(4):316-21. PubMed PMID: 26941460; PubMed Central PMCID: PMC4755706.

18: Ishii H, Zhen F, Hu M, Li X, Schnabel G. Efficacy of SDHI fungicides, including benzovindiflupyr, against Colletotrichum species. Pest Manag Sci. 2016 Oct;72(10):1844-53. doi: 10.1002/ps.4216. Epub 2016 Feb 9. PubMed PMID: 26732510.

19: Put K, Bollens T, Wäckers F, Pekas A. Non-target effects of commonly used plant protection products in roses on the predatory mite Euseius gallicus Kreiter & Tixier (Acari: Phytoseidae). Pest Manag Sci. 2016 Jul;72(7):1373-80. doi: 10.1002/ps.4162. Epub 2015 Nov 4. PubMed PMID: 26434923.

20: Mirković B, Tanović B, Stević M, Hrustić J, Mihajlović M, Delibašić G, Vukša P. Toxicity of mancozeb, chlorothalonil, captan, fluopyram, boscalid, and difenoconazole to Didymella applanata isolates from Serbia. J Environ Sci Health B. 2015;50(12):845-50. doi: 10.1080/03601234.2015.1062648. Epub 2015 Aug 7. PubMed PMID: 26252498.

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